A new class of materials that can passively harvest water from air
401 points by Tycho 1 month ago | 205 comments- gus_massa 1 month ago> a new class of nanostructured materials that can pull water from the air, collect it in pores and release it onto surfaces without the need for any external energy
As a similar comment note, it's like a high tech Dehumidifier bag. https://www.amazon.com/Wisesorb-Moisture-Eliminator-Fragranc... The bags have Calcium Chloride and absorb water from unsaturated air and make small drops of water. It's obvious that they get depleted, and to use them again you must buy a new one or boil all the water to get the crystals again.
In this new material, the droplets are attached to the material. To remove them you must use energy. They don't just drop to a bucket bellow the device magically. You can't use it to "harvest" water without energy. You can sweep the droplets with a paper towel, but now to remove the water from the paper towel you need energy.
> With a material that could potentially defy the laws of physics in their hands
This does not break the laws of physics. It would be nice that the PR department of the universities get a short course explaining that if they believe the laws of physics are broken, then they must double check with the authors and then triple check with another independent experts. Tech journalist should take the same course.
Note that the bad sentence and the misleading title is from the university https://blog.seas.upenn.edu/penn-engineers-discover-a-new-cl...
- wenc 1 month agoIt's research-in-progress, but I think the promise is slightly different from dehumidifier bags (also in other parts of the world, Thirsty Hippos [1]) which are single use.
You're correct in that: (1) it doesn't break the law of physics; (2) to remove the droplets, you still need energy. But it sounds like if the droplets are moving to the surface, the energy needed to release the droplets could be far lower than most active dehumidification methods (e.g. Peltier junctions).
[1] Thirsty Hippos -- which are very effective in small spaces.
https://www.amazon.sg/Thirsty-Hippo-Dehumidifier-Moisture-Ab...
Basically a supercharged silica gel.
- throwanem 1 month agoProbably a small piezo junction could be used to provide a solid-state vibrator for releasing water from a proportionately considerably larger area of the material, or at larger scales perhaps a technique similar to the ultrasonic sensor cleaners built into interchangeable-lens cameras.
- dieselerator 1 month agoDo you mean like an ultrasonic humidifier[1]?
[1] https://www.amazon.com/Ultrasonic-Humidifiers/s?k=Ultrasonic...
- dieselerator 1 month ago
- cryptonector 1 month agoYes this requires energy to extract the water, but if it's much less energy than dehumidifiers -say, one order of magnitude less- then it could make harvesting water from humid air economical.
- the__alchemist 1 month agoDehudifier bags (e.g. silica, CaCl) aren't single-use. Microwave, then reuse. Some even are color-changing so you know how much moisture they've absorbed.
- dotancohen 1 month agoMicrowaving is adding energy, obviously. But the idea here is that the water is recoverable, not that the air is now drier.
- incompatible 1 month agoDevices that automate this are readily available, I have one running now. "Desiccant dehumidifiers."
- dotancohen 1 month ago
- Aardwolf 1 month agoIf something breaks the laws of physics it simply means the laws of physics were incomplete, so we update them and now it no longer breaks them
- danaris 1 month agoHowever, if something claims to break the laws of physics, 99 times out of 100, it simply means that either a) the person making the claim missed something, or b) the person making the claim is lying.
- therein 1 month agoIt is really as simple as that and even applies to soon what will seem like free energy. It is not free energy, it is just energy from a field we were previously ignoring and previously fighting against.
- danaris 1 month ago
- EA-3167 1 month agoThose are usually just calcium chloride in a bag, it's very hygroscopic and fairly cheap... also makes a halfway decent de-icer. The issue I see with this thin-film method is that no mention is made of the rate of production at a given relative humidity for a given area of the film.
It's interesting, but without the details (and with a lot of PR speak) I'm skeptical as hell about this in practice.
- throwanem 1 month ago
- WalterBright 1 month agoThanks for the explanation. My first thought reading the headlines was somebody thinks they discovered a perpetual motion machine.
- galangalalgol 1 month agoWhat is the theoretical limit on the energy cost to remove water from air? A dew years back 3m had some super inexpensive way that invovled a reusable water andorber that released its water under only slightly decreased pressure and slightly increased temperature. The incoming air and the waste heat from the downstream ac unit provided all the warming with the pressure change being all that was necessary. It had two banks so one could dump water while the other absorbed. It made the whole system rund double digiymore efficient than just the ac alone. And that was neglecting that the felt temperature would be lower with the dessicated air.
- chrisweekly 1 month ago> "remove water from air? A dew years back"
"dew" was a funny typo there :)
- chrisweekly 1 month ago
- galangalalgol 1 month ago
- gsf_emergency 1 month agoThe red flags in the uni PR are not so curious compared to the ones in the paper.
From figure 4 (& backed up by simulation fig 3E) it looks like stuff begins to happen only at 97% relative humidity & after a few minutes (at micrometer scale)
https://www.science.org/doi/10.1126/sciadv.adu8349
Granted, it's almost easy enough to try at home: melt some poly gloves into "freeze dried" silica powder
- rtpg 1 month agoIs there some sort of conservation of energy question in this form of water collection that establishes some minimum amount of energy that would be required to collect 1L of water from the air?
I'd assume if the amount of energy required to collect the water is low then we're looking at something interesting.
- tsimionescu 1 month agoYes, water vapor condensing to liquid water at humidity below 100% is an exothermic reaction, and the amount of energy released is (per Google) 2259kJ/kg. So any device that wants to condense 1kg of water has to dissipate at least 2259kJ of energy somewhere, assuming it is in any way temperature-dependent (if it can keep condensing water even if it becomes hotter, then this is somewhat evaded).
For context, that amount of heat is five times the amount needed to heat 1kg of liquid water from 0° to 100°C (without thawing or boiling it). So it's not in any way a trivial amount.
- tsimionescu 1 month ago
- TimByte 1 month agoYeah, "harvesting" probably oversells it unless there's a passive or low-energy way to actually collect the water. Like, maybe coupling it with a wicking surface or capillary-driven transfer system could help, but that’s an open question.
- deadbabe 1 month agoYes it is impossible to break the laws of physics. If they appear broken then it is only because our understanding was wrong. Similar, the laws cannot be “defied”. You can only do what the universe allows, nothing more.
- dumbfounder 1 month agoSo the question is how much more efficient is it? I spend hundreds of dollars per month running dehumidifiers in my house so I am keen to know.
- strontian 1 month agoMe too! Because dust mites? Curious to share notes with you, I’m running 4 aeockys right now but they don’t seem to last long
- strontian 1 month ago
- Evidlo 1 month agoWhen a publication I was involved in got a university PR piece, they were in direct communication with us
- beloch 1 month agoUniversity PR folk are sometimes quite scientifically illiterate. Their job is basically marketing. They need to turn an esoteric, jargon heavy, and heavily qualified paper into a hype piece that the money people can understand. Everything must be a ground-breaking, world-shaking, all-time first. They sometimes make dubious claims no matter how many times you tell them not to. Ultimately, they report to the university's money people and not to researchers.
If you want science, read journals. If you want to see who is likely to get more money, read university PR releases.
- Y_Y 1 month agoAmusingly, I have the same experience as you and GP. Thee university wants to hear what the researchers have to say, but subsequently they decide independently what they're writing, strict scientific honesty be damned.
- B1FF_PSUVM 1 month agoHonesty pays no bills for professional liars.
Like diplomats, they're sent abroad to lie for their university, and the university president cries all the way to the bank for the sins of his hirelings.
- B1FF_PSUVM 1 month ago
- wenc 1 month agoI've observed the same. University science PR pieces are usually unreliable -- they are optimized toward generating buzz than scientific accuracy. They usually link to the actual science papers, but the prose is usually a stretch.
Even in this case -- "defying the laws of physics" is sensationalist narrative manufacturing.
The real claim is actually more moderate, and the research is not really close to commercial yet.
- beloch 1 month ago
- aaron695 1 month ago[dead]
- wenc 1 month ago
- hollosi 1 month agoFrom the actual paper ( https://www.science.org/doi/10.1126/sciadv.adu8349 ):
"All measurements were performed at 20° ± 0.2°C maintained by an air circulation system unless otherwise noted. The temperature of the films was controlled using a heating/cooling unit (THMS350V, Linkam Scientific Instruments, Salfords, UK) when necessary."
So the latent heat is conducted away by the cooling apparatus, it's just not explicitly stated, to sound more sensational.
- TJSomething 1 month agoAnother part from the paper that a lot of people here seem to be ignoring: "Specifically, macroscopic water droplets isothermally form when the NP size is ≤22 nm, RH is >~90%, and ϕPE ranges from 0.05 to 0.35." and "Initial water droplets that are observable under optical microscopy (~1 μm in size) appear within a few seconds after being exposed to 97% RH."
This is really moist air that's only barely short of forming dew. A lot of people are focusing on sensational "violation of physics", when it's an incremental improvement on process that happens naturally.
- TimByte 1 month agoI think the interesting bit is less about "breaking physics" and more about how finely tuned the material is to encourage this behavior without external cooling.
- vel0city 1 month agoBut there was external cooling, or am I reading "The temperature of the films was controlled" incorrectly?
- vel0city 1 month ago
- TimByte 1 month ago
- mppm 1 month agoKeeping the temperature constant with a thermostat is not an issue here. That would only explain things if the surface were kept cooler than the surrounding air (below the dew point), but from the description in the paper that does not seem to be the case. They basically claim that macroscopic droplets form spontaneously from an unsaturated vapor. And no, this is not something permitted by the second law of thermodynamics.
- dotancohen 1 month ago
If someone points out to you that your pet theory of the universe is in disagreement with Maxwell’s equations—then so much the worse for Maxwell’s equations. If it is found to be contradicted by observation—well these experimentalists do bungle things sometimes. But if your theory is found to be against the second law of thermodynamics I can give you no hope; there is nothing for it but to collapse in deepest humiliation.> And no, this is not something permitted by the second law of thermodynamics.
- lolinder 1 month ago— Sir Arthur Stanley Eddington, The Nature of the Physical World (1927)
- lolinder 1 month ago
- robertclaus 1 month agoWhile I generally agree that it sounds dubious, this argument depends on whether the entropy of the liquid in the pore is lower than the entropy of the vapor in the air in the pore. I could see a highly hydrophilic capillary restricting a vapor enough to where it has better entropy in a liquid state.
If that's true we just need to balance energy, which the cooler does.
- mppm 1 month ago> I could see a highly hydrophilic capillary restricting a vapor enough to where it has better entropy in a liquid state.
My other comment here (and and a reply to a similar question) has more detail [1], but in short: this is true for capillaries and pores, it is not true for "collectable" droplets on a flat surface.
- mppm 1 month ago
- bm62 1 month agoPractically it just means that the energy to form the droplets is coming from somewhere else, just not via cooling the surface below the dew point. For instance, you could imagine something like squeezing a material that undergoes capillary condensation to get the water out, since you'd pay the requisite energy cost via mechanical work.
- dotancohen 1 month ago
- cjbgkagh 1 month agoAh that seems to explain it to me, if instead of presenting it as breaking some physics they should have said what actually makes it useful.
My understanding of it now is that since it can work at a higher temperature in an environment where the ambient temperature is low enough the latent heat can be passively radiated away. Even if using an active heat pump the higher temperatures would allow for a more efficient process. A closed system would eventually reach an equilibrium but there is no need to maintain a closed system.
- ChuckMcM 1 month agoI think the work stands out anyway. Unlike adsorption techniques there is zero change to the mechanism which just keeps pulling water from the air. Presumably, they will put a layer of this material on aluminum to conduct the latent heat and have something that just produces water full time, without additional energy input. consider a 'cube' of fins of this stuff sitting in shade with a collection bucket underneath it. It will be interesting when they build something like that how many liters/day it can extract from ambient air and under what conditions.
Devices like that would be essential during 'wet bulb' days where the temperature and water content of the air created dangerous conditions for people. A passive device that takes no energy and just sucks water out of the air? Could be a lifesaver.
- cyberax 1 month agoTo conduct the latent heat away, the aluminum sheet needs to be below the ambient temperature of the condenser plate.
- ChuckMcM 1 month agoYou didn't read the paper did you :-). First, it isn't a "condenser" (which is kind of the cool science here) it is more of a molecular sieve that exploits two materials (one that repels, and one that attracts) the molecule in question (water). The water vapor is "forced[1]" together by the nano-structure, which result in a phase change (vapor to water) and that phase change releases heat into the nano-structure (and pushes the liquid water out to the surface) which makes the nano-structure warmer than the ambient temperature. The aluminum conducts that heat and is convectively radiating it into air on surfaces not covered with the nano-structure.
The researchers also noted that the water that was expressed to the surface of the material did not evaporate (as one would expect). There some interesting speculation as to why that is. It wasn't clear whether or not the water would move across the nano-structure if it was affected by gravity (aka dripping) but I can imagine several ways to transport it off the surface so I'm sure the researchers can too.
[1] The description in the paper is that capillary action forces the vapor into the interior of the structure where it collapses into liquid.
- nullc 1 month agoYou could coat them with an ultraemissive material and point them at the sky, if its not cloudy it will get significantly below the ambient air temp.
But the paper suggest that it will condense at ambient anyways, because it gets warmer so radiation to ambient is enough for it to work.
- ChuckMcM 1 month ago
- cyberax 1 month ago
- mleonhard 1 month agoLooking at the paper, it seems like they put some silicon-dioxide nanoparticles on a substrate, then add a plastic (poly-ethylene) layer on top and melt it (annealing). The spaces between the nanoparticles gets partially filled with plastic. The ratio of plastic to particles is the poly-ethylene volume fraction (ϕPE). They tested different fractions and found that a certain range caused the wetting behavior.
Their experiments suggest that tiny water droplets appear inside the material at 70% RH (relative humidity). If this is true, then I expect there is a way to extract the droplets using very little energy. Ideas:
- make open collection points on the film
- use ultrasound to bounce the droplets around and consolidate them
- make the film on a material that can be saturated with water so the new droplets can easily join the flow
- gopalv 1 month ago> So the latent heat is conducted away by the cooling apparatus, it's just not explicitly stated, to sound more sensational.
In theory, if that makes it hotter than ambient air in the process, that would be a good thing - usually we have to cool things down below ambient air to get moisture out.
Not a good thing if you want to measure maximum moisture extraction, but cooling something to ambient temperatures is a much easier task.
- 1 month ago
- Y_Y 1 month agoThis point is essential though! As soon as I saw the headline I knew it couldn't be the full story (there's no free osmotic lunch).
Is there a corollary to Betteridge's Law that says that popular science journalism will always overatate the result?
- delusional 1 month agoWould this not invalidate the conclusions of the paper? considering they are not just claiming to form water droplets, but that they do so isothermally.
It could still be a useful material, but the science would be bad.
- TJSomething 1 month ago
- mppm 1 month agoUnless they have buried some really important caveat somewhere in the paper [1], it really looks like they are making claims that are incompatible with the second law of thermodynamics. They claim that water droplets are condensing on their nanomaterial at constant temperature and less than 100% relative humidity. This is absolutely forbidden by thermodynamics as we understand it. Under these conditions droplets can condense within pores (forming a concave surface), but they can never form a convex droplet on a flat surface.
Their mumbo-jumbo about water being "squeezed out" onto the surface by the hydrophobic component is totally bogus as well. The condensation will just stop earlier, without overflowing. Water condensing in concave pores and being squeezed into convex droplets requires hydrostatic pressure to be positive and negative at the same time.
The possibilities I see are: 1) contaminated surfaces 2) miscalibrated relative humidity or 3) they've neglected to mention a cooling plate that keeps the material below ambient.
- a1371 1 month agoI'm not sure what's forbidden here. You don't need 100% relative humidity to grab water from the air in fact in any wood has a moisture content that in equilibrium is in relation to the air moisture content. The moisture diffuses into every material and evaporates based on where it finds less vapor pressure. That's why you may have dry lips at 40% RH versus moisturized lips at 70% RH.
What you're referring to is condensation and is caused by air oversaturation due to a temperature drop which doesn't seem to be the case here.
Theoretically speaking, you can have a material that somehow absorbs high moisture from the air but has microscale properties that promote creation of droplets then somehow these droplets are separated from the rest of the air (with something like a smart vapor retarder, a passive material) and the water gets harvested.
- mppm 1 month agoWhat you are referring to is called capillary condensation [1]. When you have a hydrophilic surface with thin capillaries or small pores, they can pull water from the air below 100% RH. However, this process requires an enclosed space with a very small radius and the air-water interface is always concave in this case (it's just how capillary forces work).
Forming a convex surface, on the other hand, requires an at least slightly hydrophobic material and produces a positive internal pressure. This is a key difference, because condensation into a hydrophilic pore is favorable in terms of free energy, while condensing onto a hydrophobic surface is unfavorable (unless you have a supersaturated vapor).
> Theoretically speaking, you can have a material that somehow absorbs high moisture from the air but has microscale properties that promote creation of droplets then somehow these droplets are separated from the rest of the air
That "somehow" is what makes the paper's claims impossible. The water condenses spontaneously into the pore because it thereby lowers its free energy. Extruding it onto the surface is then even more unfavorable than direct condensation. Unfortunately, no passive system can achieve this feat, no matter how cleverly nanostructured, as it would go against the arrow of increasing entropy. You need an external energy source to drive that process.
- Swannie 1 month agoThank you, this is a very clear explanation for me.
It filled the critical gaps in my intuition that I didn't have the brain cycles to formulate hypotheses against.
- Swannie 1 month ago
- mppm 1 month ago
- hinkley 1 month agoThe reverse problem is also true with such materials:
Water harvesting in pristine lab conditions may break down rapidly in realistic scenarios. Something that’s wet attracts dust and microbes. Dust plus water means more microbes. You’ll have lichen growing on this stuff in no time.
- TimByte 1 month agoAlso wouldn't be the first time an experiment overlooked a small temperature gradient or calibration issue
- ummonk 1 month agoDid you read the article? They're not droplets on a flat surface. They're droplets being held by surface tension to water inside pores.
- a1371 1 month ago
- vintermann 1 month agoRepost from four days ago: https://news.ycombinator.com/item?id=44060712
Also, they do a really good job of making it sound like it violates thermodynamics. Since it doesn't, and dehumidifiers already do a good job of getting water out of air for the energy price you have to pay, there has to be some other selling point. Right? But I'm not sure I see it.
- crazygringo 1 month ago> dehumidifiers already do a good job of getting water out of air for the energy price you have to pay
They do a terrible job. Condensate dehumidifiers are as expensive to run as an AC, produce unwanted heat, and are noisy. Dessicant dehumidifiers are even less energy-efficient.
If there's a way to extract moisture from the air with less energy and less noise, that would be huge.
- lolinder 1 month agoLess energy would definitely be a huge plus but unless this violates our understanding of thermodynamics there will still be unwanted heat put out into the air. The heat from a dehumidifier comes primarily from the latent heat in the water being released so that the water can become liquid. This heat must be released somehow in this process unless they actually did find something that breaks our understanding of physics.
Obligatory Technology Connections video on the topic: https://www.youtube.com/watch?v=j_QfX0SYCE8
- crazygringo 1 month agoThat's true, but I was under the impression that most of the heat generated by current compressor dehumidifiers is just waste heat from the mechanical operation of the compressor itself. The phase change heat is there too, but it's significantly less. So there should still be a lot of room for improvement, theoretically.
- leptons 1 month ago>The heat from a dehumidifier comes primarily from the latent heat in the water being released so that the water can become liquid.
A dehumidifier movies heat from one side to another using electricity to do the work. One side gets cold so the water can condense on it, while the other side gets hot from extracting the heat from the cold side. Heat is still generated from this process even if there are 0 water molecules in the air and no water is collected. The water does not create the heat, the electricity does.
I don't think there has to be any heat involved with collecting water molecules in the air into a larger volume of water, depending on the process used.
- 1 month ago
- crazygringo 1 month ago
- gus_massa 1 month ago> If there's a way to extract moisture from the air with less energy and less noise, that would be huge.
Less noise: I agree, but you still need some air flow so the corners of the room that are far away also get dehumidified. Perhaps a slow fan in enough, and when you run them slowly they are quieter.
Less energy: It's not clear that this uses less total energy. It's easier to imagine what is happening if you compare it to a high tech Dehumidifier Bag. https://www.amazon.com/Wisesorb-Moisture-Eliminator-Fragranc... But instead of sending the drops down, they get attached to the device. You can use it only once unplugged. Then you have to buy a new one or use energy to extract the water (like boiling the water of the dehumidifier bad until you get the crystals again). It's not clear if building a new copy of this is cheaper than building some new calcium chloride salts, and/or if regenerating the new device is cheaper than regenerating the calcium chloride salts (that is usually not done).
- simiones 1 month agoSo, is this new method less noisy and/or more energy efficient? The article doesn't really say.
- thfuran 1 month ago>without the need for any external energy.
That sure seems to imply that there's no need for a noisy and power hungry compressor.
- thfuran 1 month ago
- petesergeant 1 month agoEspecially for somewhere like UAE that in summer has the upsetting combination of massive humidity, no rain, and huge water demand.
- ChrisMarshallNY 1 month agoSomeone here once posted a link to a story[0] about the Persian Cooling Towers, that you see all over the ME.
Thousands of years old, I think.
[0] https://www.bbc.com/future/article/20210810-the-ancient-pers...
- ChrisMarshallNY 1 month ago
- JKCalhoun 1 month agoPerhaps OP was describing "swamp coolers" — or evaporative cooling?
- thfuran 1 month agoThat's the exact opposite of extracting moisture from the air.
- thfuran 1 month ago
- 90s_dev 1 month ago> If there's a way to extract moisture from the air with less energy and less noise, that would be huge.
I vote we write to our legislators to update the laws of thermodynamics to enable this. Typically I would agree we should leave well enough alone, but in this case it seems like the benefits outweigh the costs.
- hackyhacky 1 month agoThat's not how the laws of thermodynamics work.
In reality, you would need to convene an international consortium to approve to the change, and the Chinese wouldn't sign on unless we agree to a temporary suspension of Newton's third law.
- protocolture 1 month agoJust run it in Australia, we already overturned mathematics.
- layer8 1 month agoI’m not sure the constitution grants Congress that power.
- hackyhacky 1 month ago
- lolinder 1 month ago
- jcims 1 month agoIt almost certainly doesn't violate our understanding of thermodynamics, but it's not clear that it would have to in order to condense ambient water vapor from the atmosphere.
From the paper [1]:
Remarkably, when these amphiphilic nanoporous PINFs are exposed to high yet subsaturating conditions [i.e., relative humidity (RH) < 100%], macroscopic water droplets appear spontaneously on the film surfaces without the need for cooling, as illustrated in Fig. 1C and shown in Fig. 1D.
- BenjiWiebe 1 month agoWell, when water changes from vapor to liquid, it releases heat. The heat has to go somewhere.
Sorry, I don't know the correct physics lingo. Heat of enthalpy or formation or whatever.
- chasd00 1 month agoTangent but this may solve a mystery of mine. When I make scrambled eggs I add a little bit of water to make them fluffy. When I turn off the heat there’s a puff of steam I can’t explain. Since it seems to me more heat is needed to produce that extra puff of steam. However, maybe the fast condensing of the water vapor that happens when I turn off the stove produces a. I start of extra heat and therefore the steam?
- jcims 1 month agoSure, but it could get absorbed/radiated away in the base material.
- chasd00 1 month ago
- wrp 1 month agoIf water vapor is condensing on the material, wouldn't there be a transfer of heat energy?
- pyinstallwoes 1 month agoHeat transfer is not transfer of heat energy
- pyinstallwoes 1 month ago
- BenjiWiebe 1 month ago
- scotty79 1 month agoThe idea here is that you don't need to cool down the air to get water.
First you get water, and as a result material heats up a little bit, then it can cool down passively back to ambient.
- bayindirh 1 month ago> there has to be some other selling point. Right? But I'm not sure I see it.
Windtraps [0].
- detourdog 1 month agoor moisture vaporators
- moffkalast 1 month agoBut moisture farming? Really? A man of your talents?
- moffkalast 1 month ago
- simiones 1 month agoThose exist, but, as the GP points out, they're called "dehumidifiers". Or sometimes clothes driers. The question was, what makes this new dehumidifier any better than existing dehumidifiers.
- bayindirh 1 month agoWindtraps are passive, like this material. They work solely on temperature differential and wind.
I'm not aware of any passive, solid state dehumidifiers which are not chemical, which condense water to a chemically loaded solution, which what a Windtrap is not.
- detourdog 1 month agoThis would be passive and solid state.
- bayindirh 1 month ago
- detourdog 1 month ago
- dang 1 month ago> Repost from four days ago
Thanks! there were a few comments there and we'll merge them hither.
- crazygringo 1 month ago
- salomon812 1 month agoI wish they hadn't used "physics-defying" in their press release because I'm certain this is an important discovery for water condensers, but claiming it doesn't need an external energy source is massively negligent.
I'm fairly certain they've created some form of a Brownian Ratchet: https://en.wikipedia.org/wiki/Brownian_ratchet
People love to claim there's no external energy source, but then when you look closely, you'll find a hot-cold differential, and then you need external energy to maintain that differential. I'd put a large sum of money that either the material is colder than the ambient environment or the incoming moisture is warmer than the ambient environment. It might even be a differential within their material, and the lab lights are warming one side! There's a lot of passive devices that rely on the hot-cold cycle of day and night, that still counts as energy input from the sun.
The article even mentions they tried to rule out a thermal gradient by increasing the thickness of the material, I'm not sure I understand why that would rule it out... the gradient would still exist.
I hate this, because if they aren't intentionally supplying energy, it's probably really efficient (assuming they aren't taking samples out of the freezer or something) so it's still a big deal and important but apparently we have to claim something is a perpetual motion machine to get attention among the public.
- ajnin 1 month agoYeah I understand the need for an university to make the news once in a while, and the fact that this made the front page here proves the effectiveness of the method, but the terms "Passively Harvest" and "Defies Physics" should be used very carefully in the context of a scientific publication, even though it's only a blog post so we don't expect peer-reviewed journal levels of rigor.
I feel that it disserves science in the end, the belief that some magic material is going to break the second law of thermodynamics is closer to alchemy than chemistry.
- abracadaniel 1 month agoPET is a decent insulator, and they seem to be trying to ensure it wasn’t the temperature difference causing condensation, but the nano structure itself. I’m assuming they were controlling temperature and humidity, so it would mean the material must get hotter, but that seems like it can also be passively solved with a radiator. What they are describing would be a pretty big deal and seems plausible.
- ajnin 1 month ago
- andrewrn 1 month agoThis is pretty cool! Basically changes the thermodynamic delta required for a condensation-evaporation cycle from climatic mediation to material mediation.
What if you could eventually program the pore size? This would mean you could change the inflow/outflow balance of the reservoirs on-demand. Imagine smart clothing. Hot out -> increase pore size so the material dumps water, cold out -> pore size shrinks so the water is less likely to evaporate.
I am peeved by the "violates physics" verbiage in the article though.
- PaulHoule 1 month agoSee https://en.wikipedia.org/wiki/Air_well_(condenser) and https://en.wikipedia.org/wiki/Fog_collection and https://en.wikipedia.org/wiki/Atmospheric_water_generator
- scotty79 1 month agoThis apparently can collect vapor (not fog) in ambient temperature, although the material heats up a little bit while absorbing water and needs to cool back down, which should be fine since when warm it's warmer than ambient air.
- kayodelycaon 1 month agoAll of those rely on condensation, which is caused by temperature getting low enough the air can’t hold water. The mechanism for the new material is completely different. It doesn’t appear to require the air to be saturated.
We already have substances that remove water from air. In those the water becomes absorbed. This seems to work on a similar principle. The real difference is the water doesn’t stay absorbed.
- Quarrel 1 month agoI'm so tempted to link this..
Like, not even ironically.
I know this isn't reddit and all, but, well..
- vasco 1 month agoDew collectors are used in agriculture in deserts for real and I think in Dune too. Shaun Overton has a youtube channel where he's trying to revitalize a piece of desert and he has tried building some.
- downboots 1 month agoNot sure why it's downvoted. Fiction isn't as far from reality.
- vasco 1 month ago
- scotty79 1 month ago
- elil17 1 month agoPeople need to understand that the minimum energy required to separate water from air is much higher than the minimum energy required to separate water from salt. This fact of physics means desalination will always be more efficient than water harvesting.
- rtpg 1 month agoMy understanding is that with desalination you now have the problem of all the brine (on top of needing a good amount of consumable material to do the desalination when looking at existing products).
Seems to me that if you have a device that requires no extra material consumable input that's pretty interesting? Plenty of places with access to electricity that could benefit from the lack of other material input in theory.
- crazygringo 1 month agoDoes that include transportation costs?
If you have power, you can harvest water from the air wherever you are. Desalination generally requires trucking the water from the ocean to you.
I don't have the slightest idea whether transportation costs can ever be large enough to make water harvesting more efficient?
- rtpg 1 month ago
- davedigerati 1 month agoWith respect to energy balance comments and comparing this to other technologies: both processes of absorption and condensation are happening within the same material passively, meaning you do not need to put energy into it. The heat gained from absorption is lost in the next step of condensation. The impact of this discovery, therefore, is that you don't need the power of your AC or your dehumidifier or your moisture vaporator on the south ridge.
Always testing the AI's I thought this might be a fun one to watch how they think through it since it is about technology that they would not have been trained on. Grok thought through the process more thoroughly than I (B.S.ChemE) would've .
https://grok.com/share/bGVnYWN5_e80e8100-3682-4157-879e-c5ca...
- gus_massa 1 month agoGrok is wrong. The description violates the second law of thermodynamics. But I don't blame Grok, the PR is very misleading.
- gus_massa 1 month ago
- lightedman 1 month agoWe did something similar to this in the middle of the Mojave with carbonate rock, charcoal, and a big corrugated metal tube.
It produces about 3 gallons of water a night.
34.997387, -116.380048
See the big tube sticking up? There's a miner's hotel built there.
- fblp 1 month agoGot a link to how this was made?
- lightedman 1 month agoI do not, I'm sorry. Basically the bottom is charcoal for a filter, the top is porous carbonate rock to catch moisture from the air, and the large metal tube serves as a way to heat things up and then at night chill down below ambient a bit faster so that water condenses out of the rock and drips through the charcoal and through piping to a water collection system.
- lightedman 1 month ago
- fblp 1 month ago
- fuddy 1 month agoI think people are being too critical in the comments.. I see nothing requiring free energy or physics defying in an ideal condensation material. This process is going on all the time in less optimized materials and we usually are not happy about it. (There's also a very interesting logical argument that we only exist because the water molecule has such unusual properties compared to its environment.)
- Elaris 1 month agoIf this technology can be widely applied in water scarce areas, it would be incredibly meaningful. People in these regions would no longer have to worry about water shortages. It could truly change lives by providing access to clean water without relying on external resources, making a significant impact on communities that need it the most.
- ggm 1 month agoMangle, looped band of material. Energy can be totally mechanical to move the loop through the mangle, or PV harvested electrical.
There's no free lunch, but removing water from a fabric matrix is a well understood process. Thats what washerwomen have done for millenia.
- bilsbie 1 month agoI hope this pans out. There are 1000s of applications:
Put one of these next to every tree. Or lines of them along rows of crops.
Run one in homes to make your ac more efficient and manage humidity.
Collect water on mountains or tall buildings and make hydro power?
Keep your pool topped off.
- TimByte 1 month agoI love that it's not just about absorption but this continuous cycle of condensation and release. That's what makes it potentially useful beyond niche cases.
- circles_for-day 1 month agoThis seems like it could be improved with ai-assisted molecular dynamics that have been in the news for drug discovery and protein folding.
- bilsbie 1 month agoCould this lead to a superior desalination method?
Basically Let salt water saturate the air in a closed system and use these to collect the water.
- DocTomoe 1 month agoNow make this a marketable power-less air dehumidifier. This is one of those 'changing whole industries' things.
- WalterGR 1 month agoThose exist in the form of dehumidifier bags, and they're inexpensive and easy to get. Does this material have benefits over what's currently in use?
- DocTomoe 1 month agoDehumidifier bags are bulky. Surfaces, on the other side, can be folded into loops, which should increase the amount of humidity they can absorb.
- the__alchemist 1 month agoSurfaces as you describe go into the bags.
- the__alchemist 1 month ago
- DocTomoe 1 month ago
- WalterGR 1 month ago
- ChiMan 1 month agoUses in AC and clothing seem like obvious use cases.
- scubadude 1 month agoRemoving water from the atmosphere on scale can only be devastating to global weather patterns. Sorry country B, you get no more rain because country A is harvesting all the water.
- fuzzfactor 1 month agoNever quit experimenting on something worthwhile, for one thing so you're always experimenting.
The best things may come by accident, which is where it sometimes just starts to get good.
But what are the difference in odds for someone who is constantly experimenting versus someone who experiments not at all?
Regardless of what you really set out to accomplish to begin with.
And which has the momentum to continue experimenting, even in the case of a major pivot?
Looks like they really have hit the sweet spot and it's a bit like creating molecular sieves which are tuned to release the collected moisture without excess energy.
Could also be harvesting a little ambient energy and working to "zone refine" the atmospheric fluid.
- dfilppi 1 month ago[dead]
- 1 month ago
- wheelerwj 1 month agoIs it just me or does extracting moisture from the air seem like a really bad idea?
- B1FF_PSUVM 1 month agoI take it you do not live on the south or east coast of a northern hemisphere continent?
People there usually have a surplus of moisture in the air most of the time.
- wheelerwj 1 month agoA surplus according to who? Those ecosystems exist for a reason. Are we talking about terraforming Earth? For what purpose?
- wheelerwj 1 month ago
- B1FF_PSUVM 1 month ago
- mistrial9 1 month agothis was certainly amazing to see (at least two years ago)